My understanding is if it's working, you should see a message in the upper corner when launching a compatible game. You should also be able to see a list of available achievements in the PSCX2 pause menu while the game is running.
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Sometimes you can do things like a GDPR request your cloud saves from Sony, then see if the Palworld save files are in any way transferable to PC.
This doesn't usually work, but it's really nice if it does.